Photocatalysis with Semiconductor Materials

Abstract

IIn this work stability of photocurrent of two photoelectrochemical cells (PECs) and photocatalytic activity for photocleavage of water in few aqueous semiconductor suspensions are investigated.

It is found that a thin layer of p-CuCNS suppress photocorrosion of CU 2O photocathode in aqueous thiocynate. In the other PEC, highly stable photocurrent was achieved by deposition of two dyes on the CuCNS substrate. When CuCNS is coated with a dye that can transfer a charge carrier upon exitation into an energy band if a layer of a second dye that can readily transfer the energy of photon exitations into the inner one by resonance is deposited on top of the first dye, then photodegradation of both dyes are suppressed.

Three aqueous photocatalytic systems based on Ag2 O/Ag, CUCI2 /CuCl and Hg 20/Hg redox couples are found to photo-oxidise water into oxygen and hydrogen by a cyclic two photosystem process in the presence of sensitizer (eg.TiC2). In each system, the redox couples act as the electron pool linking the two photosystems.

β - form p-CuCNS was found to photo-oxidise water in the presence of sacrificial agents more readily than most materials generally used for this purpose. When p-CuCNS coated with dye and then platinized, photogenerates oxygen with the dye remaining photostable. Again a suspension of Hg2 Cl2 in aqueous HgCl2 photogenerates oxygen reducing Hg2Cl2 to Hg2Cl2- In absence of an electron acceptor Hg photogenerate oxygen from water degrading into Hg. A number of heavy metal hexacyanides are also tested for their ability to catalyse photo-oxidation of water with bipy3 Ri2+ as the sensitizer and K2S2O8 as the electron donor. Strongest catalytic activity is seen in Zn3(Fe(CN6)2 and Cd3(Fe(CN)6)2.